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Should sunglasses be worn for driving?
Sunglasses are the favorite "necessary accessory" worn by drivers to reduce glare and increase comfort during driving. Under bright conditions sunglasses are very helpful to drivers to reduce the brightness and glare, thereby allowing better vision under those driving conditions.
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Medium to dark lenses are used for driving, picnicking, and general purpose sunglass use. The important aspect to remember in selecting the darkness of a lens is to let comfort and visibility in the expected use conditions, be your guide. A caution, however, extremely dark lenses (below 8% visible transmittance) should not be used for driving.
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Can polarized sunglasses help when driving a car?
Yes. Those pesky bright reflections of the sun on the cars ahead can sometimes be attenuated a good deal. They tend to be horizontally polarized, thus perfect for vertically polarized sunglasses. The reason is that the surfaces that you see on the car in front of you (the back window, the trunk door, and even the roof) will be slanted towards you, while the sun will be more or less aligned in the vertical plane through both cars (if not you wouldn't see its reflection from those surfaces). However, if the sun is relatively low behind you, the sun rays will be near perpendicular to the reflecting (vertical) surfaces which won't polarize the light. The sunglasses will help more with the reflections from the glass than from the metal as the former are polarized to a higher degree.
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What about the brightness of the road itself?
That light is also partially polarized, but by scattering (as opposed to reflection). The direction of polarization will change with the direction of the road with respect to the position of the sun. The rule is that the polarization is tangential to a circle centered on the sun. That means that if the sun is in front, behind, or high above, the road brightness will tend to be horizontally polarized and the filter of the sunglasses will provide some help. However, if the sun is to one side, the polarization will rotate vertically the lower the sun happens to be. Of course, if the road is wet you get the same anti-glare power as at sea.
Tinting   
The color of the tint determines the parts of the light spectrum that are absorbed by the lenses. Manufacturers use different colors to produce specific results.
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Mirroring
Reflective sunglasses often have a mirrored look. The lenses in these sunglasses have a reflective coating applied in a very thin, sparse layer -- so thin that it's called a half-silvered surface.
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The name "half-silvered" comes from the fact that the reflective molecules coat the glass so sparsely that only about half the molecules needed to make the glass an opaque mirror are applied. At the molecular level, there are reflective molecules speckled all over the glass in an even film but only half of the glass is covered. The half-silvered surface will reflect about half the light that strikes its surface, while letting the other half go straight through.
Often, the mirror coating is applied as a gradient that gradually changes shades from top to bottom. This provides additional protection from light coming from above while allowing more light to come in from below or straight ahead. What that means is that if you are driving, the sun's rays are blocked but you can see the dashboard. Sometimes the coating is bi-gradient, shading from mirrored at top and bottom to clear in the middle.
The key problem with reflective sunglasses is that the coating is easily scratched. Apparently, sunglass manufacturers have not been able to successfully apply a scratch-resistant layer on top of the reflective coating. Therefore, the scratch-resistant coating is applied first to protect the lenses and the reflective coating is applied over it.
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